chemistry ONLINE TEST 0% 12th Chemistry One Mark Test – Full Portion Wish you all the Best ! 1 / 70 Which of the metal is extracted by Hall-Heroult process? Zn Al Cu Ni 2 / 70 The magnetic moment of Mn²⁺ ion is? 8.95BM 5.92BM 2.80BM 3.90BM 3 / 70 Collodion is a 4% solution of which one of the following compounds in alcohol – ether mixture? Nitroglycerine Cellulose acetate Nitrocellulose Glycoldinitrate 4 / 70 Which one of the following compounds is not formed? XeOF₄ NeF₂ XeF₂ XeO₃ 5 / 70 Most easily liquefiable gas is? Kr Ar Ne He 6 / 70 Electrochemical process is used to extract? Silver Lead Iron Sodium 7 / 70 In calcium fluoride, having the fluorite structure the coordination number of ion and Ion are? 6 and 6 4 and 2 8 and 4 4 and 8 8 / 70 The rate constant of a reaction is 5.8 × 10ˉ² sˉ¹ . The order of the reaction is? First order zero order Second order Third order 9 / 70 Nitrobenzene on reaction with Con HNO₃ / H₂ SO₄ at 80-100⁰C forms which one of the following products? 1,4 – dinitrobenzene 1,2 – dinitrobenzene 2,4,6 – tirnitrobenzene 1,3 – dinitrobenzene 10 / 70 Which one of the following undergoes reaction with 50% sodium hydroxide solution to give the corresponding alcohol and acid? Phenylmethanal ethanal methanol ethanol 11 / 70 On reacting with neutral ferric chloride, phenol gives? no colouration red colour violet colour dark green colour 12 / 70 Carbolic acid is? benzoic acid phenylacetic acid Picric acid Phenol 13 / 70 Conjugate base for Bronsted acids H₂ O and HF are? OH⁻ and H₂ FH⁺ , respectively OH⁻ and F⁻ , respectively H₃ O⁺ and F⁻ , respectively H₃O⁺ and H₂ F⁺ , respectively 14 / 70 Oxidation state of Iron and the charge on the ligand NO in [Fe (H₂O)₅ NO] SO₄ are? +3 and -1 respectively +2 and 0 respectively +1 and +1 respectively +3 and 0 respectively 15 / 70 Cupellation is a process used for the refining of? Lead Copper Silver Iron 16 / 70 Faradays constant is defined as? charge carried by one mole of electrons charge required to deposit one mole of substance charge carried by 6.22 ×10¹⁰ electrons. charge carried by 1 electron 17 / 70 On hydrolysis, PCl₃ gives? POCl ₃ H₃ PO ₃ H₃ PO₄ PH₃ 18 / 70 What is the activation energy for a reaction if its rate doubles when the temperature is raised from 200K to 400K? (R = 8.314 JKˉ¹molˉ¹)? 2.305 kJ molˉ¹ 234.65 kJ molˉ¹Kˉ¹ 334.65 J molˉ¹Kˉ¹ 434.65 kJ molˉ¹Kˉ¹ 19 / 70 Zinc can be coated on iron to produce galvanized iron but the reverse is not possible. It is because? Zinc is lighter than iron Zinc has lower melting point than iron Zinc has lower negative electrode potential than iron Zinc has higher negative electrode potential than iron 20 / 70 Graphite and diamond are ? both molecular crystals ionic and covalent crystals both covalent crystals Covalent and molecular crystals 21 / 70 Solid CO₂ is an example of ? Covalent solid molecular solid ionic solid metallic solid 22 / 70 Which one of the following characteristics are associated with adsorption? ΔG is negative but ΔH and ΔS are positive ΔG and ΔHare negative but ΔS is positive ΔG, ΔH and ΔS all are negative ΔGand ΔS are negative but ΔH is positive 23 / 70 Which of the following metals has the largest abundance in the earth’s crust? Magnesium Aluminium Sodium Calcium 24 / 70 Which one of the following is an example for homogeneous catalysis? Hydrolysis of sucrose in presence of dil HCl manufacture of ammonia by Haber’s process hydrogenation of oil manufacture of sulphuric acid by contact process 25 / 70 Which of the following is not SP2 hybridised? Fullerene Graphene Dry ice Graphite 26 / 70 The ratio of close packed atoms to tetrahedral hole in cubic packing is? 1 : 4 2 : 1 1 : 2 1 : 1 27 / 70 In the extraction of aluminium from alumina by electrolysis, cryolite is added to? Remove impurities from alumina Lower the melting point of alumina Decrease the electrical conductivity Increase the rate of reduction 28 / 70 Wolframite ore is seprated from tinstone by the process of? Roasting Calcination Electromagnetic separation Smelting 29 / 70 The reagent used to distinguish between acetaldehyde and benzaldehyde is? 2,4 – dinitrophenyl hydrazine semicarbazide Tollens reagent Fehling’s solution 30 / 70 Which one of the following statements related to lanthanons is incorrect? Ce⁴⁺ solutions are widely used as oxidising agents in volumetric analysis. The basicity decreases as the ionic radius decreases from Pr to Lu. Europium shows +2 oxidation state. All the lanthanons are much more reactive than aluminium. 31 / 70 Which one of the following reaction is an example of disproportionation reaction? none of these cannizaro reaction Aldol condensation Benzoin condensation 32 / 70 Which of the following fluro compounds is most likely to behave as a Lewis base? PF₃ CF₄ SiF₄ BF₃ 33 / 70 A magnetic moment of 1.73BM will be shown by one among the following? TiCl₄ [ Ni (CN)₄]²⁻ [CoCl₆]⁴⁻ [ Cu (NH₃)₄]²⁺ 34 / 70 The vacant space in bcc lattice unit cell is ? 26% 32% 48% 23% 35 / 70 An excess of silver nitrate is added to 100ml of a 0.01M solution of pentaaquachloridochromium(III)chloride. The number of moles of AgCl precipitated would be? 0.2 0.02 0.01 0.002 36 / 70 The correct statement regarding RNA and DNA respectively is? the sugar component in RNA is ribose and the sugar component in DNA is 2’-deoxyribose the sugar component in RNA is an arabinos and the sugar component in DNA is ribose the sugar component in RNA is 2’-deoxyribose and the sugar component in DNA is arabinose the sugar component in RNA is an arabinose and the sugar component in DNA is 2’-deoxyribose 37 / 70 The phenomenon observed when a beam of light is passed through a colloidal solution is? Tyndall effect Coagulation Cataphoresis Electrophoresis 38 / 70 During electrolysis of molten sodium chloride, the time required to produce 0.1mole of chlorine gas using a current of 3A is? 220 minutes 55 minutes 330 minutes 107.2 minutes 39 / 70 Which of the following is incorrect for physisorption? low heat of adsorption increases with increase in surface area reversible increases with increase in temperature 40 / 70 In acid medium, potassium permanganate oxidizes oxalic acid to? acetate Carbon dioxide acetic acid oxalate 41 / 70 Which of the following reagent can be used to convert nitrobenzene to aniline? Zn/NH₄Cl ZnHg / NaOH Sn / HCl All of these 42 / 70 The product formed by the reaction an aldehyde with a primary amine? carboxylic acid aromatic acid schiff ’s base ketone 43 / 70 An elements belongs to group 15 and 3 rd period of the periodic table, its electronic configuration would be? 1s² 2s² 2p³ 1s² 2s² 2p⁶ 3s² 3p³ 1s² 2s² 2p⁶ 3s² 3p² 1s² 2s² 2p⁴ 44 / 70 In a protein, various amino acids linked together by? Peptide bond Dative bond β – Glycosidic bond α – Glycosidic bond 45 / 70 The number of electrons that have a total charge of 9650 coulombs is? 6.022 x 10²² 6.022 x 10⁻³⁴ 6.22 x 10²³ 6.022 x 10²⁴ 46 / 70 The formation of cyanohydrin from acetone is an example of? nucleophilic substitution Nucleophilic addition electrophilic substitution electrophilic addition 47 / 70 The addition of a catalyst during a chemical reaction alters which of the following quantities? Activation energy Internal energy Enthalpy Entropy 48 / 70 Oxidation state of carbon in its hybrides? +3 -4 +2 +4 49 / 70 The geometry at which carbon atom in diamond are bonded to each other is? Hexagonal Octahedral None of these Tetrahedral 50 / 70 Which one of the following rotates the plane polarized light towards left? D(+) Galactose D(+) Glucose D(-) Fructose L(+) Glucose 51 / 70 The decomposition of phosphine (PH₃) on tungsten at low pressure is a first order reaction. It is because the? rate is independent of the surface coverage rate is inversely proportional to the surface coverage rate is proportional to the surface coverage rate of decomposition is slow 52 / 70 The central dogma of molecular genetics states that the genetic information flows from? DNA → Carbohydrates → Proteins DNA → RNA → Carbohydrates DNA → RNA → Proteins Amino acids → Protein → DNA 53 / 70 What is the pH of the resulting solution when equal volumes of 0.1M NaOH and 0.01M HCl are mixed? 7.0 2.0 3 12.65 54 / 70 Secondary nitro alkanes react with nitrous acid to form? red solution yellow solution blue solution green solution 55 / 70 Which of the following compound can be used as artifreeze in automobile radiators? methanol Neopentyl alcohol ethan -1, 2-diol ethanol 56 / 70 In aqueous solution of amino acids mostly exists in? NH2-CH(R)-COO NH2-CH(R)-COOH H3N+-CH(R)-COOH H3N+-CH(R)-COO- 57 / 70 Which one of the following is the strongest acid? 3 – nitrophenol 4 – chlorophenol 2 – nitrophenol 4 – nitrophenol 58 / 70 While charging lead storage battery? PbSO₄ on cathode is reduced to Pb PbSO₄ on anode is reduced to Pb PbSO₄ on anode is oxidised to PbO₂ PbSO₄ on cathode is oxidised to Pb 59 / 70 The sum of primary valance and secondary valance of the metal M in the complex [ M(en)₂ (Ox) ] Cl is L? -3 6 9 3 60 / 70 Concentration of the Ag⁺ ions in a saturated solution of Ag₂ C₂ O₄ is 2.24 ×10⁻⁴ mol L⁻¹ solubility product of Ag₂ C₂ O₄ is? 2.66 x 10⁻¹² mol³ L⁻³ 5.619 10⁻¹² mol³ L⁻³ 4.5 x 10⁻¹¹ mol³ L⁻³ 2.42 x 10⁻⁸ mol³ L⁻³ 61 / 70 Which one of the following reduces tollens reagent? none of these benzophenone acetic acid formic acid 62 / 70 Among the following, which is the strong gest oxidizing agent? I₂ F₂ Br₂ Cl₂ 63 / 70 Which of the following d block element has half filled penultimate d sub shell as well as half filled valence sub shell? None of these Cr Pd Pt 64 / 70 Boric acid is an because its molecule? Contains replaceable H+ ion Gives up a proton Combines with proton to form water molecule Accepts OH- from water,releasing proton. 65 / 70 If the initial concentration of the reactant is doubled, the time for half reaction is also doubled. Then the order of the reaction is? Fraction One None Zero 66 / 70 Which one of the following will not undergo Hofmann bromamide reaction? CH₃ CH₂ CONH₂ CH₃ CONHCH₃ C₆ H₅ CONH₂ CH₃ CONH₂ 67 / 70 Permanganate ion changes to ________ in acidic medium? Mn²⁺ Mn³⁺ MnO₂ MnO₄²⁻ 68 / 70 Which one given below is a non-reducing sugar? Lactose. Glucose maltose Sucrose 69 / 70 Which of the following compounds on reaction with methyl magnesium bromide will give tertiary alcohol? methyl propanoate acetaldehyde propanoic acid benzaldehyde 70 / 70 Which one of the following will give a pair of enantiomorphs? [Cr(NH₃)₆] [Co(CN)₆] [Pt(NH₃)₄] [PtCl₄] [Co(en)₂ Cl₂] Cl [Co(NH₃)₄ Cl₂] NO₂ Your score is Note: Once you start the test, you are not allowed to go back. 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